The Recombination Luminescence of Tryptophan in Aqueous Glasses, I Quenching Effect of Electron Scavengers

نویسنده

  • Shozi Yamashita
چکیده

The quenching effect of Se(>4— and NO3(scavenger for trapped electrons) on the delayed luminescence ('recombination luminescence') caused by the recombination of trapped electrons with mother tryptophan cations was investigated in aqueous 9 M NaOH and 9.5 M LiCI glasses at 77 K . The results show that the trapped electrons responsible for the recombination fluorescence were deep-trapped ones in 9 M NaOH glasses and shallowand deep-trapped ones in 9.5 M LiCI glasses. However, trapped electrons participating in the recombination phosphorescence were almost shallow-trapped ones in the two glasses. The distribution of the trapped electrons is discussed.

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تاریخ انتشار 2012